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Existence Criterion of Three-Dimensional Regular Copper-1,3,5-Phenyltricarboxylate (Cu-BTC) Microparticles

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【作者】 杨成飞高东杰何吉欢

【Author】 YANG Chengfei;GAO Dongjie;HE Jihuan;National Engineering Laboratory for Modern Silk,College of Textile and Clothing Engineering,SoochowUniversity;School of Mathematics and Statistics ,Heze University;School of Science ,Xi’an University of Architecture and Technology;

【通讯作者】 何吉欢;

【机构】 National Engineering Laboratory for Modern Silk,College of Textile and Clothing Engineering,Soochow UniversitySchool of Mathematics and Statistics ,Heze UniversitySchool of Science ,Xi’an University of Architecture and Technology

【摘要】 Nano or micro-scale particles are considered as a zero-dimensional material, and their shape is difficult to control. Here the crystal-like microparticles are formed, and the existence criterion of crystal-like low dimensional materials is established. The hydrothermal method is used to fabricate copper-1,3,5-phenyltricarboxylate(Cu-BTC) microparticles, which have a regular geometric shape with regular triangle, quadrangle and hexagon. The benzene ring and carboxyls(—COOH) attached to the benzene ring form two basic molecular structures of [Cu3(BTC)2]n, which play an essential role in the construction of a three-dimensional crystal-like structure.

【基金】 National Natural Science Foundation of China(No.11372205)
  • 【分类号】TB383.1
  • 【下载频次】3
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