摘要：A new cobalt（Ⅱ） coordination polymer with the formula of [Co（iqnc）2]n（1, iqnc = l-isoquinolinecarboxylate） has been synthesized through hydrothermal synthesis and structurally characterized by single-crystal X-ray diffraction method. The title coordination polymer represents a two-dimensional layer structure featuring adjacent one-dimensional [Co（iqnc）2]n chains connected with each other by uncoordinated oxygen atoms of carboxylate. Crystal data: monoclinic, space group P21/c, a = 15.4302（2）, b = 5.6743（7）, c = 9.2307（1） ?, β = 98.459（2）o, V = 799.41（2） ?3, Z = 2, S = 1.019, the final R = 0.0346, w R = 0.0876（I ＞ 2σ（I）） and R = 0.0477 and wR = 0.1159 for all reflections. In addition, elemental analysis, IR, and magnetism properties are presented.
基金资助：
Supported by the National Natural Science Foundation of China（No.21203160）； Education Department Foundation of Shaanxi Province（No.12JK0631）； Natural Science Foundation of Shaanxi Province（No.2013JM2013）； Special Research Fund of Xianyang Normal University（No.11XSYK204,11XSYK205,12XSYK023）；
- DOI：
10.14102/j.cnki.0254-5861.2011-0708
- 专辑：
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- 分类号：
O641.4
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