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Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands

LI Wen-BinGAO Zhu-QingGU Jin-Zhong

School of Chemical and Biological Engineering,Taiyuan University of Science and TechnologyCollege of Chemistry and Chemical Engineering,Lanzhou University

摘要:One new mixed-ligand coordination polymer,namely[Co2(btc)(bpdc)0.5(py)3]n(1),was hydrothermally synthesized using biphenyl-2,4,4’-tricarboxylic acid(H3btc) as a main building block,along with two auxiliary ligands(H2bpdc = 2,2’-bipyridine-5,5’-dicarboxylic acid and py =pyridine).The product 1 was characterized by IR spectroscopy,elemental,thermogravimetric,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction studies show that compound 1 possesses an intricate 3D metal-organic framework based on tetracobalt(Ⅱ) units.Magnetic susceptibility measurement indicates that compound 1 shows an antiferromagnetic coupling between the Co(Ⅱ) ions.
  • DOI:

    10.14102/j.cnki.0254-5861.2011-0929

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  • 分类号:

    O641.4

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