Synthesis,Crystal Structure and Properties of a Zinc(Ⅱ) Complex Based on 5-(1H-Tetrazol-5-yl)isophthalic Acid Ligand
张兴晶王璐瑶尉兵李梦乔宇车广波
College of Chemistry,Jilin Normal University Key Laboratory of Preparation and Applications of Environmental Friendly Materials,Chinese Ministry of Education,Jilin Normal University
摘要:A novel polymeric zinc(II) complex {[Zn2(TIA)(H2O)3]?(NO3)}n(1, H3TIA = 5-(1H-tetrazol-5-yl)isophthalic acid) has been synthesized in mixed solvents under solvothermal conditions and characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction. Complex 1 crystallizes in orthorhombic, space group Cmcm with a = 10.4210(6), b =23.3526(14), c = 6.9214(4) ?, V = 1684.37(17) ?3, Z = 4, C9H4N5O10Zn2, Mr = 472.91, Dc = 1.865g/cm~3, F(000) = 932, λ(MoK α) = 2.909 mm-1, R = 0.0423 and wR = 0.1287. The complex has good thermal stability and excellent photoluminescent property.
基金资助:
Supported by the National Natural Science Foundation of China(No.21576112); the Program for New Century Excellent Talents in University(NCET-10-0176)of China; Natural Science Foundation Project of Jilin Province(No.20130521019JH and 201215219);
- DOI:
10.14102/j.cnki.0254-5861.2011-1029
- 专辑:
- 专题:
- 分类号:
O641.4
引文网络
- 参考文献
- 引证文献
- 共引文献
- 同被引文献
- 二级参考文献
- 二级引证文献
相关推荐
- 相似文献
- 读者推荐
- 相关基金文献
- 关联作者
- 相关视频