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Synthesis,Crystal Structure and Photoluminescent Property of a Novel Dy3+ Coordination Compound Containing Rare(H2O)22 Clusters

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【作者】 叶燕珠吴新建张贤金汪阿恋

【Author】 YE Yan-Zhu;WU Xin-Jian;ZHANG Xian-Jin;WANG A-Lian;Department of Science Research and Training,Fujian Institute of Education;

【机构】 Department of Science Research and Training,Fujian Institute of Education

【摘要】 A novel Dy3+ coordination compound,(H2pipz)(H3O)[Dy(pydc)3]·11H2O(1,pipz = piperazine and H2pydc = pyridine-2,6-dicarboxylic acid),has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction,elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O···H···O hydrogen bonding interactions. Furthermore,the luminescent property of compound 1 was also investigated.

【基金】 financially supported by the Foundation of Fujian Educational Committee(JA14348)
【所属期刊栏目】 organometallic structural chemistry (2016年12期)
  • 【DOI】10.14102/j.cnki.0254-5861.2011-1418
  • 【分类号】O641.4
  • 【被引频次】2
  • 【下载频次】27
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